Abstract
Abstract New epoxide monomers have been prepared that contain allylic chlorine. These have been copolymerized with propylene oxide to give polymers that also contain allylic chlorine. This type of propylene oxide rubber can be vulcanized with a mixture of magnesium oxide and zinc oxide eliminating the need for sulfur in the vulcanization recipe. This work presents an indirect proof of the allylic structure of neoprene and substantiates the theory of vulcanization of neoprene by magnesium and zinc oxides.
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