Preparation of dual-use GPTES@ZnO photocatalyst from waste warm filter cake and evaluation of its synergic photocatalytic degradation for air-water purification

Abstract

Organic pollutants are the most critical threats to the health of air and water resources. On this basis, fabricating a photocatalytic acrylic film with dual-use (i.e. removing benzene from air and MB/MO dyes from water) was aimed in this research. For this purpose, waste warm filter cake (WWFC) was used to extract zinc from it. Zinc element was separated from WWFC by a basic leaching method and acidified to prepare zinc oxide nanoparticles. In the following, a simple hydrothermal method was used to increase the surface functionality of the extracted ZnO nanoparticles in order to establish active reaction sites for reaction to silane coupling agent and increase in the holes that were prepared during photo-excitation. Thereafter, the nanoparticles were modified with 3-glycidoxypropyltriethoxysilane (GPTES) at different concentrations. The band gap of the modified nanoparticles decreased from 3.25 to 3.1 eV by surface modification. The photocatalytic performance of ZnO nanoparticles was assessed by degradation of MB and MO aqueous solution (50 ppm) under simulated UV/Visible irradiations. MB and MO were degraded 91 and 60% under UV light and 65 and 50% under visible light after 150 min of irradiation. The photo degradation rate increased after adding carboxy methyl cellulose (CMC) surfactant to methylene blue and adding cocamide-dea (CDE-G) surfactant to methyl orange. The results confirmed that the green surfactants improve the dispersion and surface interaction of the modified nanoparticles in the dyes solution and cause more electron charge transfer which creates effective photocatalytic sites. The prepared nanocomposite films were placed in a photo-reactor to remove gaseous benzene from air under UV/visible irradiation. Gas chromatography (GC) results showed that the modified nanoparticles removed up to 35.25 and 20.34% of benzene from air. Colorimetric analysis (ΔE*) showed that the acrylic film contained modified nanoparticles degraded 91 and 82% of MB, and 85 and 76% of MO under UV/visible lights, respectively. In the end, it can be said that these photocatalytic films are able to remove environmental pollution in air and water.