Year-end Sale % OFF 
Abstract
Abstract Optically active aminophosphines were prepared via ortho-directed metalation of appropriate arylamines followed by introduction of a diphenylphosphino group. These aminophosphines were used as ligands in the rhodium complex-catalyzed asymmetric hydrogenation of itaconic acid. Although moderate optical yields (up to 43% ee) were obtained, the stereochemical outcome with each ligand depended markedly on the chelate effect of the aminophosphines which played a significant role in both catalytic activity and enantioselectivity.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
