Preparation of Carbon-Alumina (C/Al2O3) aerogel nanocomposite for benzene adsorption from flow gas in fixed bed reactor

Abstract

Benzene is one of the hazardous environmental pollutants which have harmful effects on human, animal and environmental health. the goal of this study was to synthesize a carbon/alumina aerogel with large surface area, which is easily recoverable and can be used as an adsorbent for benzene removal from the polluted air flow. The composite aerogel was dried at ambient temperature for 48 h and at 120 °C for 48 h in a sequential way. The characteristic properties of the composite aerogel were analyzed using Brunauer-Emmett-Teller (BET), Scanning Electron Microscopy (SEM), Barrett-Joyner-Halenda (BJH) method and energy-dispersive X-Ray (EDX) techniques. The findings of this study showed that, with increasing of the inlet flow rate from 0.2 l/min to 0.5 and 0.8 l/min, the breakthrough time decreased from 13 h to 7 and 3 h, respectively., Besides, the amount of adsorption capacity on aerogel nanocomposite decreased from 126.73 mg g−1 to 84.5 and 38 mgg−1 with increasing the inlet benzene concentration from 100 ppmv to 200 and 300 ppmv, respectively. In addition, the a carbon/alumina aerogel can be exploited for removing other pollutants from air and water.Recently, the adsorption process has attracted many research attentions for Benzene removal from different applications due to some inherent characteristics such as low-cost and high feasibility.•The results indicated that the synthesis of the composite aerogel have been successfully performed.•The composite aerogel was synthesized by combining Novollac with alumina, which had high surface area and suitable benzene adsorption ability.