Abstract

Bi0.85Nd0.15FeO3 (BNF) nanotube arrays were prepared by a sol–gel template method. The microstructure and phase were observed by scanning electron microscopy and transmission electron microscopy. Highly ordered nanotube arrays with BNF nanotubes of 200 nm diameter, 60 μm length, and 20 nm wall thickness were obtained. The BNF nanotube array capacitor showed ferroelectricity with a remanent polarization (2P r) of 68.7 μC/cm2 and a coercive electric field (2E c) of 141.9 kV/cm at frequency of 1000 Hz. The leakage current behavior of the BNF nanotube array was dominated by an ohmic conduction mechanism at E < 30 kV/cm and a space-charge-limited current mechanism at E = 30 kV/cm to 200 kV/cm.

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