Abstract
AbstractA simple convenient method has been developed for the preparation of N‐acetyl‐S‐arylcysteines based on the Chan–Lam–Evans arylation of N,N′‐diacetylcystine dimethyl ester with arylboronic acids and used to synthesize a series of arylmercapturic acids. Unlike copper‐mediated N‐arylation, the S‐arylation of neither cysteine nor cystine derivatives proceeded satisfactorily in the presence of air.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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