Preparation of Adsorbent Based on Polyacrylate Latex Solid Waste and Its Application in the Treatment of Dye Wastewater.

Abstract

It is a great challenge to sustainably produce and apply water-based coatings and inks in terms of realizing the green resource utilization of polyacrylate latex solid waste (PLSW) and avoid its secondary pollution. In this paper, a kind of high value-added amphoteric ion-exchange resin (AIER) was prepared by using diethylenetriamine to amidate PLSW under the optimized conditions from a Box-Behnken design. Its adsorption and regeneration properties and the universality of the method were investigated. The results suggested that AIER possessed a high removal efficiency to anionic dyes, and the batch dye adsorption processes were endothermic and spontaneous, which is consistent with a pseudo-second-order kinetic model. The penetration adsorption capacities of AIER were recorded to be 987.08 mg/g for RR239 and 1037.75 mg/g for RB5 at the optimized operating conditions of column height = 6.4 cm, flow rate = 1 mL/min, and dye solution of 500 mg/L. They were more than 200 times larger than that of commercial activated carbon when the mixture composed of AIER particle and diatomite particle (filter aid agent) was used as a fixed-bed adsorbent. Zeta potential analysis results indicated that the good adsorption and regeneration performances of AIER were mainly attributed to the presence of amino and carboxyl groups in the molecular structure of AIER. Most importantly, this method possessed excellent practicability and universality for different types of PLSW from factory wastewater. The results provide a feasible method and theoretical basis for the green resource utilization of PLSW, and the goal of “waste control by waste” was fundamentally achieved.