Abstract
Activated ceria (CeO2/γ-Al2O3) prepared by impregnation was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and hydrogen temperature-programmed reduction (TPR). The desulfurization of the activated ceria was investigated by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TG). The results showed that ceria could be highly dispersed or crystallized on the surface of γ-alumina. The reduction temperatures of 0.1CeO2/γ-Al2O3, 0.45CeO2/γ-Al2O3, and CeO2 ranged from 250°C to 470°C, 330°C to 550°C, and 350°C to 550°C, respectively. The reduction peak temperature of 0.45CeO2/γ-Al2O3 was higher than that of 0.1CeO2/γ-Al2O3, which was consistent with the reduction temperature of CeO2. O2 participated in the reaction between ceria and sulfur dioxide. The desulfurization product was cerium(III) sulfate. The intensity of the hydroxyl band decreased with the formation of sulfate species.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
