Preparation of a thin-film nanocomposite forward osmosis membrane for the removal of organic micro-pollutants from aqueous solutions

Abstract

ABSTRACT In this study, a thin-film nanocomposite forward osmosis (TFN FO) membrane was synthesized. The properties and structures of membranes were evaluated for the removal of three organic micro-pollutants from synthetic and real industrial wastewater samples. Laboratory scale fabrication thin-film nanocomposite forward osmosis (FO) membranes composed of a support layer and an active layer. The former was constructed by adding different weight ratios of polyethylene glycol 400 (PEG-400) (0–8 wt.%), polysulfone (PSf), and 1-methyl, 2-pyrrolidone via the phase inversion process, while the latter was synthesized by the incorporation of different weight ratios of graphene oxide (GO) (0–0.012 wt.%), M-phenylenediamine, and 1, 3, 5-benzene trichloride into polyamide layer through the interfacial polymerization reaction. In comparison with thin-film composite (TFC) membranes, the TFN membranes revealed higher hydrophilicity, porosity, water permeability, water flux and salt rejection and lower internal concentration polarization (ICP), reverse salt flux and specific reverse salt flux. The TFN membrane containing 0.008% GO in the active layer and 4% PEG 400 in the support layer exhibited maximum water flux (34.3 LMH) and rejection rate of benzene, phenol and toluene (97%, 84%, and 91%, respectively). The results revealed that the TFN-FO membranes possess a promising potential to improve the water flux and wastewater treatment.