Preparation of a high-coordinated-silicon-centered spiro-cyclic compound.

Abstract

Silicon compounds containing silicon-silicon bond with a variety of unusual oxidation states are quite important, because their high reactivity leads to the formation of a variety of silicon compounds. The isolation of such compounds with unusual oxidation states requires a resilient synthetic strategy. Herein, we report the synthesis of a silicon based spirocyclic compound containing a hyper-valent silicon atom and a silicon-silicon bond. The computational calculations employing natural bond orbital (NBO) analysis and energy decomposition analysis-natural orbitals for chemical valence (EDA-NOCV) reveal that the nature of bonding between the silicon atoms is of an electron sharing nature.