Preparation of 2D Graphene/MXene nanocomposite for the electrochemical determination of hazardous bisphenol A in plastic products

Abstract

Bisphenol A (BPA) is one of the major contaminants with significant health hazards, which could also affect the endocrine system or induce cancer. It is essential to develop a highly sensitive and selective BPA sensor for environmental and food safety. Herein, 2D hybrid graphene/Ti3C2Tx nanocomposite (Gr/MXene) was prepared via a top-down method and then used to fabricate an electrochemical BPA sensor. The X-ray diffraction spectrometer (XRD) and Raman spectroscopy analysis were carried out to verify the successful formation of Gr sheets with MXene. The high resolution scanning electron microscopy (HR-SEM) was revealed the formation of MXene, and Gr/MXene nanocomposite. Furthermore, the 2D hybrid Gr/MXene nanocomposite modified glassy carbon electrode (GCE) was prepared for BPA oxidation in 100 mM phosphate buffer solution (PBS). Under the optimized condition, the Gr/MXene/GCE was displayed a linear range of detection from 10 to 180 nM and 1 to 10 μM BPA with the detection limits of 4.08 nM and 0.35 μM by amperometry and differential pulse voltammetry (DPV), respectively. Moreover, the proposed Gr/MXene modified electrode exhibited excellent stability, selectivity, repeatability and reproducibility towards the BPA detection. As a proof of concept, Gr/MXene modified sensor was effectively used to detect BPA in modern plastic products with the recovery ranging from 99.2 to 104.5%.