Preparation of α-halo- F-2-ketones and F-2-ketones via fluorination of α,α-dihalo- F-2-ketones

Donald J Burton,Howa Jeong In

doi:10.1016/s0022-1139(00)80488-1

Preparation of α-halo- F-2-ketones and F-2-ketones via fluorination of α,α-dihalo- F-2-ketones

Donald J Burton, Howa Jeong In

https://doi.org/10.1016/s0022-1139(00)80488-1

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Journal: Journal of Fluorine Chemistry	Publication Date: Nov 1, 1993
Citations: 10

Affiliation: University of Iowa

#Antimony Pentafluoride #Excellent Yields

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Abstract

Fluorination of α,α-dichloro- F-2-ketones with antimony pentafluoride provided excellent yields of α-chloro- F-2- ketones and F-2-ketones regioselectively. However, fluorination of α,α-dibromo- F-2-ketones with antimony pentafluoride gave a mixture of α-bromo- F-2-ketones and F-2-ketones.

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