Abstract
In the present work, we synthesized a new hybrid compound, (C6H10N2)2 Cd3Cl10. The crystal structure, vibrational and photoluminescence properties of the compound were studied. The structure can be described by the alternation of two different cationic-anionic layers. It consists of Cd3Cl10 dimers anions and bis orthophenylenediammonium (C6H10N2) cations, which are connected via NH⋯Cl hydrogen bonds forming a chain network. Furthermore, the 3D Hirshfild surfaces and the associated 2D fingerprint plots were investigated for intermolecular interactions in the molecule. The X ray powder is in agreement with the x ray structure. The Infrared Spectrum recorded in the 4000-400 cm−1 frequency region was compared with those found in homologous compounds in the literature. 13C Nuclear magnetic resonance (NMR) spectrum shows three signals, confirming the solid state structure determined by X-ray diffraction. Finally the characteristic exciton peaks in absorption spectra are located at 252 and 494 cm−1 and the photoluminescence measurements showed one peak at around 2.06 eV.
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