Preparation, Microwave Absorption and Infrared Emissivity of Ni-doped ZnO/Al Powders by Coprecipitation Method in the GHz Range

Abstract

In this work, Ni-doped ZnO/Al composites were prepared by a facile chemical co-precipitation method. The morphology and structure of the as-prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS), respectively. It was found that the flake-like Al powders were successfully coated by Ni-doped ZnO nanoparticles with slight aggregation and Ni[Formula: see text] was successfully doped into the crystal lattice of ZnO. Moreover, the effects of ZnO concentration and doped Ni concentration on the infrared emissivity of ZnO/Al composites at the waveband range of 8–14[Formula: see text][Formula: see text]m were studied. The results showed that the ZnO/Al composites exhibited the lowest infrared emissivity of 0.34 with 50[Formula: see text]wt.% ZnO concentration. Meanwhile, the electromagnetic parameters and microwave absorbing properties of Ni-doped ZnO/Al composites in the frequency range of 2–18[Formula: see text]GHz were explored. Significantly, 12[Formula: see text]mol.% Ni-doped ZnO/Al composites presented the lowest infrared emissivity of 0.37 and the maximum reflection loss reached [Formula: see text]32.5[Formula: see text]dB at 13.6[Formula: see text]GHz with a thickness of 4.5[Formula: see text]mm. The excellent microwave absorbing properties could be attributed to the good impedance match, crystal lattice defects and interfacial polarization. It was believed that the Ni-doped ZnO/Al composites could be used as potential infrared-microwave compatible stealth materials.