Abstract
Two novel coordination polymers, [Cu(PDCO)·(H2O)]n(1) and [Cd(PDCO)(bipy)·(H2O)·5H2O]n(2), (H2PDCO=pyridine-3,5-dicarboxylic acid N-oxide, bipy=4,4′-bipyridine), have been synthesized under hydrothermal conditions, and their structures were determined by single-crystal X-ray diffraction studies. Polymer 1 features a three-dimensional (3D) network with nonequivalent nodes of (63)2(69·85·10) topology. Polymer 2 exhibits one-dimensional (1D) double-stranded chains. The magnetic character of 1 as well as the gas adsorption and luminescent properties of 2 have been investigated.
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