Abstract
Two kinds of rare earth (RE) complexes were intercalated into zirconium bis(monohydrogenphosphate) (α-ZrP) by exchanging the RE complexes into the p-methyoxyaniline (PMA) preintercalated compound Zr(O3POH)2·2PMA (α-ZrP·2PMA). Powder X-ray diffraction patterns reveal that Eu(DBM)3phen (DBM: dibenzoylmethane, phen: 1,10-phenanthroline) and Tb(AA)3phen (AA: acetylacetone) intercalated into α-ZrP·2PMA. This was confirmed by the UV-visible spectra of both the RE complexes and the assemblies. At the same time, the assemblies have better luminescent properties, and the fluorescent lifetimes of RE3+ in the excited state in the assemblies are much longer than those in the complexes. The stabilities of the assemblies under UV radiation are much better than those of the RE complexes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
