Preparation, characterization and photocatalytic activity of a novel nanostructure composite film derived from nanopowder TiO 2 and sol–gel process using organic dispersant

Abstract

A novel sol–gel-derived titanium dioxide nanostructure composite has been prepared by spin-coating and investigated for the purpose of producing films. The processing of the composite sol–gel photocatalysts involved utilizing of precalcinated nanopowder titanium dioxide as filler mixed with sol and heat treated. The sol solution was prepared by adding titanium tetra isopropoxide (Ti(OPr) 4 or TTP) to a mixture of ethanol and HCl 35.5% (mole ratio TTP:HCl:EtOH:H 2O = 1:1.1:10:10), then a solution of 2 wt% methylcellulose was added and stirred at room temperature. Precalcinated TiO 2 nanopowder was dispersed in the sol and the prepared mixture was deposited on the microscope glass slide by spin-coating. The inhomogeneity problem in preparation of composite film which causes peeling off and cracking after calcination due to the shrinkage of the films with thermal treatment were overcome by using methylcellulose (MC) as a dispersant. The composite heat treated at approximately 500 °C has the greatest hardness value. Surface morphology of composite deposits by scanning electron microscopy (SEM) showed remarkable increase in the composite surface area. Evaluation of the adhesion and bonding strength between the coating and substrate was carried out by the scratch test technique. The minimum load which caused the complete coating removal, for composite thick film was 200 g/mm 2 which indicates a strong bond to the substrate. Photocatalytic activity of the composite film was evaluated through the degradation of a textile dye, Light Yellow X6G (C.I. Reactive Yellow 2) as a model pollutant and were compared with those of similar composite thick film without MC, thin film of TiO 2 and TiO 2 nanopowder. The results show that the photocatalytic activity and stability of the composite films are higher than those of nanopowder TiO 2. However, a remarkable increase in the composite surface and good mechanical integrity make this composite film a viable alternative for commercial applications.