Abstract
An intermolecular compound, H3PMo12O40·5(CH3CH2)2NH·H2O, between the heteropolymolybdate α-H3PMo12O40 and the organic substrate diethylamine, has been synthesized and characterized. Light yellow crystals of the title compound were crystallized from a mixed solvent of water and acetonitrile with formula H3PMo12O40·5(CH3CH2)2NH·H2O. Spectroscopic data support the presence of a sizable electronic interaction between the organic substrate and the inorganic anion in the solid state. The single crystal x-ray structure analysis of the title compound revealed that it crystallized in the triclinic system, space group P\(\overline 1\) with a = 12.0786(13), b = 12.102(5), c = 21.416(3) A, α = 94.87(2), β = 94.755(9), γ = 113.81(2)°, V = 2830.3(13) A3, and Z = 2.
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