Abstract
AbstractSeveral novel kinds of bis‐quaternary ammonium peroxotungstates and peroxomolybdates, such as PhCH2N(CH2CH2)3NCH2Ph[W2O3(O2)4], PhCH2N(CH2CH2)3NCH2Ph [Mo2O3(O2)4], [PhCH2(CH3)2NCH2]2[W2O3(O2)4] and [PhCH2(CH3)2NCH2]2[Mo2O3(O2)4], have been synthesized and characterized by elemental analysis, IR and Raman spectroscopy. Their catalytic properties in mild oxidation of benzyl alcohol and ring‐substituted benzyl alcohols were investigated with aqueous 30% H2O2 under halide‐ and organic solvent‐free conditions. Copyright © 2007 John Wiley & Sons, Ltd.
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