Preparation, Characterization and Application of Silver Chloride-Eosin Y Inclusion Material

Abstract

Abstract From the adsorptive precipitation of Cl–, eosin Y (EY) and Ag+, we developed in-situ inclusion of EY into growing silver chloride particles to form ternary electronegative micro-conductors. The composition of the particles was determined by inductively coupled plasma atomic emission spectrometry (ICP-OES), ion chromatography (IC) and spectrophotometry and the size and pattern of the particles characterized by the particle size analysis, X-ray diffractometer (XRD), scanning electron microscopy (SEM), and thermogravimetry. The results showed that the in-situ inclusion of EY into AgCl crystal particles in layer-by-layer and the supermolecular complex {[(AgCl)50EY]n}2n– was formed in cubic and globe-like shape. The ternary inclusion particles adsorbed cationic dyes selectively, rapidly and with high efficiency. A representative cationic dye, victoria blue B (VBB), was used to investigate the performance of the ternary particles as adsorbents and the mechanism involved. The equilibrium adsorption capacity of the ternary particles is 353 mg/g VBB, over 10 times higher than absorption to the silver chloride–only particles and over 3 times to activated carbon. Moreover, the adsorption approached the equilibrium in 10 min, which is much less than that with activated carbon in about 2 h. This work advanced a sample method for preparation of the supramolecular inclusion materials as dye adsorbent and it provided a simple, efficient and practical approach for the recovery or removal of organic substances from aqueous.