Preparation, characterization and application of a new kind of mesoporous composite

Abstract

The composite oxide CuO/Mn 3O 4 and its mesoporous composite were prepared through co-precipitation method. The preparation conditions of CuO/Mn 3O 4 were tested and ascertained as following: Mn:Cu, 2:1; NaOH solution, 25% (w/w); volume, 6 mL; without aging; drying temperature, 90 °C; calcination temperature, 200 °C; calcination time, 3 h. CuO/Mn 3O 4, the mesoporous solid, and the mesoporous composite were characterized by X-ray power diffraction (XRD), high-resolution transmission electron microscope (HRTEM). The HRTEM image showed that CuO/Mn 3O 4 had been loaded into the pores of the mesoporous solid and the average diameter of CuO/Mn 3O 4 particles was about 4 nm. The specific surface area and the aperture distribution of the mesoporous solid and the mesoporous composite were measured by N 2 adsorption. The catalytic activity and stability of CuO/Mn 3O 4 and the mesoporous composite were evaluated on a small fixed reaction bed and an online GC. The tar and some other harmful components in cigarette smoke can be reduced by using dual-filters containing the mesoporous composite. Comparing with the reference cigarette smoke, the tar, CO, benzo[α] pyrene and tobacco-specific N-nitrosoamines (TSNAs) in the tested cigarette smoke were reduced by 27.2, 23.8, 30.1, and 38.1%, respectively.