Abstract

Oil deposited on shoreline substrates has serious adverse effects on the coastal environment and can persist for a long time. In this study, a green and effective microemulsion (ME) derived from vegetable oil was developed as a washing fluid to remove stranded oil from beach sand. The pseudo-ternary phase diagrams of the castor oil/water (without or without NaCl)/Triton X-100/ethanol were constructed to determine ME regions, and they also demonstrated that the phase behaviors of ME systems were almost independent of salinity. ME-A and ME-B exhibited high oil removal performance, low surfactant residues, and economic benefits, which were determined to be the W/O microstructure. Under optimal operation conditions, the oil removal efficiencies for both ME systems were 84.3 % and 86.8 %, respectively. Moreover, the reusability evaluation showed that the ME system still had over 70 % oil removal rates, even though it was used six times, implying its sustainability and reliability.

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