Abstract
Reaction of Ti(OPr i ) 4 with propan-2-one, under initially anhydrous conditions, yields a colourless moisture-sensitive crystalline product which is structurally identified as the trinuclear oxoalkoxide [Ti 3 O{µ-OPr i ) 3 (OPr i ) 4 {Me 2 C(O)CHC(O)CH 2 C(O)Me 2 }] containing a coordinated C 9 ligand derived from the condensation of propan-2-one.
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