Preparation and Upconversion Emission Investigation of the YVO4: Yb3+/Tb3+/Eu3+ Nanomaterials and Their Coupling with the Au Nanoparticles

Abstract

AbstractThe YVO4 nanomaterials doped with the Yb3+/Tb3+/Eu3+ ions and their mixture with the Au nanoparticles are synthetized with a classical sol‐gel method. With the excitation of a 975 nm laser, both the doped YVO4 sample and the corresponding mixture sample have a series of upconversion emission peaks of Eu3+ and Tb3+, which includes the 5D0→7Fj transitions of the Eu3+ ions and the 5D4→7Fj transitions of the Tb3+ ions. The slope values of the log‐log plots of laser power dependence for the upconversion emission intensities range from 1 to 2, which confirms that the upconversion process is a two‐photon process. With the plasmon coupling, the slope value for the power dependence of the magnetic dipole transition 5D0→7F1 of the Eu3+ ions decreases from 1.4 to 1.1, while it increases for other electric dipole transitions. Because of the plasmon coupling, the emission peak of the Eu3+ at about 2.095 eV decreases significantly and almost cannot be observed. Meanwhile, the emission peak of the Tb3+ at about 2.113 eV increases significantly and becomes the main emission peak in the yellow band. This phenomenon confirms that there is different mechanism for the magnetic and electric dipole emission with the plasmon coupling.