Abstract

Abstract This paper focuses on thermal stability of molten salts, operating temperature range and latent heat of molten salts at a high temperature. In this experiment, multi-component molten salts (purified Solar Salt) composed of purified NaNO3 and purified KNO3 were prepared by statical mixing method. Compared with unpurified Solar Salt, purified Solar Salt had a higher thermal stability. The optimal temperature would be increased from 500°C to 550°C, and the upper limitation temperature increases from 577.5°C to 593.7°C. Meanwhile, thermal stability and thermal cycling analysis showed the purified Solar Salt had a lower melting point and the deterioration time of molten salts was reduced. The melting point of purified Solar Salt decreases sharply to 223.8°C and the latent heat increases from 74.39 J/g to 80.79 J/g. Besides, the XRD and chemical analysis test indicated that the degree of degradation reduced and the thermal storage efficiency of purified Solar Salt was improved.

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