Abstract

A wet chemical process has been developed for the preparation of a leadindium phosphate compound, and the effect of incorporation of aluminum into the compound on the thermal properties of the resulting glass is reported. High field 27Al NMR in combination with a magic angle spinning technique was used to investigate the aluminum coordination in the leadindiumaluminum phosphate glass. The transition, crystallization and softening temperatures and thermal expansion coefficient of the glass were determined by means of DTA, TMA and dilatometric measurements.

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