Abstract
An eight-coordinated Cd (II) complex, bis (N,N’-phenanthroline)-bis (O,O’-nitrate) Cd (II) (1), was synthesized using 1, 10-phenanthroline and cadmium nitrate tetrahydrate as raw materials. The structural analyses of Cd(II) complex 1 shows that the compound 1 belongs to monoclinic, space group C12/c1 (no.15) with a = 11.4490(5) Å, b = 15.3716 (6) Å, c = 13.2153 (6) Å, β = 102.892 (5)º, V=2267.13 (17) Å3, Z = 4, Dc = 1.749 mg·m−3, μ = 1.020 mm−1, F(000) = 1192, and final R1 = 0.0392, ωR2 = 0.0827. The Cd (II) complex 1 forms 1D chained structure by the π-π interaction of phenanthroline rings..
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