Abstract
Some trimethylsilyl esters of N- phenyl-N- alkyl- (methyl-, ethyl-, n propyl-, i propyl-, n butyl-, t butyl-) carbamic acids were prepared by a novel method. Their solvolysis with isopropanol was studied. UV spectrophotometry was used to monitor the reaction and the pseudo first order rate constants were determined.A reaction mechanism is suggested on the basis of the dependence of rates on the ionic strength, on the temperature, on the isotope effect and on the concentration of various additives (sodium isopropoxide, sodium hydroxide, triethylamine and its hydrochloride, respectively).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
