Abstract
The reaction of [Cp ★Ru(OMe)] 2 ( 1) with PCy 3 yields the 16-electron alkoxo derivative, Cp ★Ru(OMe)(PCy 3) ( 2). 2 reacts with H 2 and HBF 4 to give the known Cp ★RuH 3PCy 3 ( 3) and [Cp ★Ru(C 6H 9PCy 2)]BF 4 ( 4). The reaction of 1 with one or two equivalents of L yields Cp ★RuHL 2 (L = PCyPh 2 ( 5), PCy 2H ( 6)) through a β-elimination process. Upon protonation, 5 and 6 are converted into [Cp ★RuH 2L 2]BF 4 (L = PCyPh 2 ( 7), PCy 2H ( 8)).
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