Abstract
γ,γ-Dialkoxyallylic zirconium species can be easily prepared from the reaction of triethyl orthoacrylate with zirconocene equivalent (zirconocene-butene complex). This species reacts with aldehydes as an α,β-unsaturated acyl anion equivalent to give the 1-substituted-2,2-diethoxy-3-buten-1-ol derivatives.
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