Abstract
Abstract Complexes [VX2(salen)] (X = Cl, Br) are reduced by hydrazines to give either [VX(salen)(ROH)]ROH (R = Me, Et) or [{VX(salen)}2], depending on the solvent. Treatment of [VO(salen)] with I2 in acetonitrile gives I5− or I7− salts of the [{V(salen)}2(μ-O)]+ cation, which are reduced by diethylaluminium ethoxide in the presence of phenylhydrazine, to give [V(PhNHNH2)2(salen)]I.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.