Abstract
Abstract Waterborne castor oil-based polyurethane-silica hybrid materials with chemically bonded polymer matrix and silica nanoparticles were designed and prepared. The formation of cross-linking structures in the waterborne polyurethane system was confirmed by Fourier transform infrared spectroscopy. Transmission electron microscopy images indicated that nano-silica was encapsulated by polyurethane and exhibited an apparent core–shell structure. The nano-silica in the polyurethane matrix was vital in improving both the hydrophobicity and thermal stability of the resulting hybrid polyurethane films. With increased silicone content, the roughness, hydrophobicity, and thermal stability of the films were enhanced, but the transparency of the films in the 300–800 nm region was decreased. These results can aid in the design of bio-based hydrophobic waterborne polyurethane films with favorable thermal stability and optical transmittance.
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