Abstract
The reactions of bis(trifluoromethyl)tellurium and bis(trifluoromethyl) tellurium dihalides with Lewis acids and bases are reported. Bis(trifluoromethyl)tellurium dihalides react with Lewis acids AX and Lewis bases MX to yield the corresponding salts, as shown in the following scheme: ▪ As F 5 oxidizes (CF 3) 2Te in a first step to (CF 3) 2TeF 2, which in a second step reacts with an excess of AsF 5 to form the salt [(CF 3) 2TeF][AsFe 6]. The reactions of (CF 3) 2Te with alkali halides yield 1:1 complexes. The chemical properties as well as the 19F n.m.r., the Raman and the IR spectra of the new compounds will be described and compared with the corresponding iodine compounds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
