Abstract
A series of tris(p-alkylaryl)phosphines with straight chain alkyl groups, P(p-C6H4–CnH2n+1)3 where n= 2–9, have been prepared by reaction of phosphorus trichloride with the Grignard reagent derived from the corresponding p-bromoalkylbenzene. When n= 2 and 3 the phosphines are crystalline solids, but for n > 3 they are viscous oils up to n= 9, which is a waxy solid. The phosphines have been characterised by microanalysis, and i.r., 1H and 31P n.m.r., and mass spectrometry. The p-substituted-arylphosphines are more sensitive than triphenylphosphine to air; aerial oxidation converts them exclusively into the corresponding phosphine oxide, in contrast to trialkylphosphines which are oxidised to a complex mixture of products. The complexing ability of the new phosphines (PAr3) is demonstrated by their ready displacement of 1,5-cyclo-octadiene (cod) from [M(cod)Cl2](M = Pd and Pt) to yield trans-[Pd(PAr3)2Cl2] and cis-[Pt(PAr3)2Cl2], respectively.
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