Preparation and properties of poly(L-lactic acid) blends with excellent low-temperature toughness by blending acrylic ester based impact resistance agent

Abstract

Poly(L-lactic acid) (PLLA) blends with excellent low-temperature toughness and strength were prepared by melt compounding with acrylic ester based impact resistance agent (AEIR). The morphology, thermal properties, mechanical properties and biodegradability of the blends were investigated. Morphology observations revealed the blend was immiscible but had good compatibility with the dispersed phase size of about 200–300 nm. With the addition of AEIR, dramatic improvement in toughness of PLLA was achieved in a wide temperature range, especially at low temperatures the tensile strength was effectively remained. For the blend with 20 wt% AEIR, the tensile strength, elongation at break and impact strength were 51.6 MPa, 72% and 77.1 KJ/m2 at −20 °C, respectively, much greater than that reported. The calculated Tg of AEIR was lower than the test temperatures, and the brittle-tough transition occurred. The PLLA matrix demonstrated obvious shear yielding which induced energy dissipation and therefore lead to excellent toughness of the blends. Moreover, the biodegradation of PLLA was enhanced after blends preparation.