Abstract
On reaction with diironnonacarbonyl in refluxing ether, 2,5-dihydrothiophene-1-oxide forms an iron tricarbonyl complex in which the ligand has not undergone rearrangement. The iron tricarbonyl complex is formed from an intermediate that appears to be a tetracarbonyl complex in which the iron is bonded to the sulfoxide, but not to the double bond of 2,5-dihydrothiophene-1-oxide. Some reactions of the tricarbonyl complex have been examined.
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