Abstract

AbstractA two stage drawing procedure is described for producing highly oriented polymeric materials. The high orientation of both the crystalline and amorphous phase in the semi‐crystalline materials studied resulted in the materials possessing high mechanical properties. The ability to obtain high amorphous orientation is critical. Tensile strengths of 16 g/denier for polyethylene are determined, for example. The results suggest that the existence of a prominent crystalline dispersion mechanism (as observed in dynamical mechanical studies) is not necessary for the attainment of high mechanical properties. Thus a method was devised for the determination of the optimum drawing temperature.

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