Preparation and properties of gel-type low-temperature phase change materials

Abstract

In the context of the dual‑carbon target, there is a high emphasis on the energy efficiency of traditional mechanical cold storage systems with significant power consumption. Additionally, the implementation of time-of-use electricity pricing has played a crucial role in driving the rapid advancement of energy storage technology. The application of energy storage technology in cold storage can significantly reduce the energy consumption of the refrigeration system, save operating costs by shifting peak demand to valleys, and reduce start and stop frequencies. Therefore, studying phase-change materials with high latent heat, low cost, and good performance for cold storage is of great practical application in cold storage. The paper developed four types of gel-type phase-change cold storage materials with high latent heat, low cost, and good cycle stability. These materials mainly consist of NH4Cl, KCl, and deionized water. The phase transition temperature ranges from −18 to −21 °C, the latent heat of phase change is approximately 260 to 289 J/g, and the thermal conductivity ranges from 0.58 to 0.60 W/(m·K), which can meet the cooling demand of cold storage facilities. Furthermore, by comparing the phase transition temperature, latent heat value of phase change, and cyclic stability, a gel-type PCM with good comprehensive properties was selected for corrosion and corrosion inhibition studies with five common metal samples in welded and non-welded forms. The results showed that material B2 had slight corrosion on 1060 aluminum, 6061 aluminum, and 304 stainless steels, but no obvious corrosion phenomenon was found on 316 stainless steels. The corrosion rate of the material on red copper was the highest, and the corrosion was too strong. In addition, the corrosion of welded parts is more serious than that of non-welded parts, and the welding points are more susceptible to corrosion. Adding the corrosion inhibitor BTA to material B2 can reduce the corrosion rate of red copper by more than 94 %.