Preparation and properties of cyclic olefin copolymers multiwalled carbon nanotube nanocomposites

Abstract

AbstractNanocomposites of cyclic olefin copolymer (COC) and two types of multiwalled carbon nanotubes (MWCNTs) with different aspect ratios were prepared. The morphology, thermal behavior, and electrical conductivity of the nanocomposites were investigated by scanning electron microscopy, differential scanning calorimetry, thermal gravimetric analysis, and the DC conductivity measurement. It was found that the developed nanocomposite preparation method resulted in good nanotubes dispersion in the polymer matrix for both types of MWCNTs. No appreciable differences in glass transition temperatures were observed between the pure COC and nanocomposites. On the other hand, CNTs significantly improved the thermo‐oxidative stability of the COC. The nanocomposites showed significant delay in onset of degradation and the degradation temperature was ∼ 40°C higher than that of the pure COC. The nanocomposites also showed substantially higher DC conductivity, which increased with the nanotube concentration and aspect ratio. An increase of DC electrical conductivity over 109 times can be achieved by the addition of 2 wt % CNTs. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012