Preparation and properties of AlN ceramic suspension for non-aqueous gel casting

Abstract

A non-aqueous gel casting process based on the mixed solvent (ethanol and polyethylene glycol) and low-toxicity N,N-dimethylacrylamide (DMAA) was developed for an aluminum nitride (AlN) ceramic. In the present work, rheological properties of non-aqueous concentrated AlN suspensions were investigated in the presence of mixed solvent, dispersant, milling time, monomer and solid loading, in order to screen for the most suitable experimental conditions to obtain a good rheological behavior for gel casting. The results showed that the 50vol% slurry with 0.2wt% dispersant concentration, 2h milling time, 6wt% -monomer content, and a solvent ratio of 3:1, can meet the requirements for the casting process of AlN ceramic slurries. After being dried at 100°C for 1h, the optimum bulk density and maximum flexural strength of the AlN green bodies were as high as 1.97g/cm3 and 18.68MPa, respectively. SEM photographs revealed that the green body had a relative uniform microstructure when the solid loading was 50vol%. The shrinkage and deformation of shaped sintered bodies prepared through gel casting were small after sintering. The sintering shrinkage, apparent porosity, bulk density and flexural strength were 14.8%, 0.22%, 3.21g/cm3 and 310MPa, respectively.