Preparation and performance of lipophilic α-zirconium phosphate with high thermal stability and its application in thermal-plastic polymers

Abstract

To prepare lipophilic α-zirconium phosphate with high grafting ratio and thermal stability (OZrP-HT) and explore its potential application in thermal-plastic polymers, a novel method was developed by surface lipophilicity enhancement strategy. The commercial α-zirconium phosphate (α-ZrP) was pre-intercalated by n-propylamine (PA) and grafted by silane coupling agents. Then the pre-intercalated PA was removed by heat-treatment, and the obtained OZrP-HT was utilized to fabricate the phosphorous-containing polyester (P-co-PET)/OZrP-HT nanocomposites by melt-blending method. The prepared OZrP-HT and P-co-PET/OZrP-HT nanocomposites were characterized by Wide Angle X-ray Diffraction (WAXD), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Transmission Electron Microscope (TEM), etc. The results show that OZrP-HT with high grafting ratio (13.78wt%) and thermal stability (Tonset=368°C) was successfully prepared via this novel method and was uniformly intercalated by P-co-PET molecular chains. OZrP-HT had no significant effect on the fiber processability of P-co-PET polymer, and flame retardant properties of (P-co-PET)/OZrP-HT nanocomposites were improved. This method may be suitable for organic modification of general inorganic layered compounds and could extend the potential applications in thermo-plastic polymers.