Abstract
Three membrane electrodes for supercapacitors in micro-electro-mechanical-systems (MEMS) were made of polypyrrole (PPy), carbon nanotube/polypyrrole (CNT/PPy) and graphene/polypyrrole (GR/PPy) electrodeposited on current collectors. The samples were characterized by scanning electron microscopy, electrochemical impedance spectroscopy, cyclic voltammetry and galvanostatic charge/discharge. Results indicate that there are strong adhesive forces between the electrode materials and the current collectors. The electrode resistances decrease in the order of PPy, CNT/PPy and GR/PPy. The specific capacitances are 7.0, 8.0 and 8.3 mF/cm 2 at a discharge current of 1mA and their retention rates after 5000 charge/discharge cycles are 72.9%, 85.0% and 89.2% for PPy, CNT/PPy and GR/PPy, respectively. The electrochemical performance and stability of the MEMS supercapacitors are improved significantly by adding CNTs or graphene to PPy. [New Carbon Materials 2013, 28(6): 414–420]
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