Preparation and performance of 10 wt% of chlorantraniliprole Nano-suspension concentrate (SC) using polyether amine-bridged sulfonated alkali lignin (PSAL) as a dispersant

Abstract

Polyether amine-bridged sulfonated alkali lignin (PSAL) with different sulfonic group contents and molecular weights was firstly synthesized and characterized. Then, 10 wt% of chlorantraniliprole Nano-suspension concentrate (SC) was prepared by the water-based grinding method, and the optimum grinding parameters were explored and obtained. Based on this optimum grinding formula, chlorantraniliprole Nano-SC was prepared and three optimum dispersants were finally obtained as follows: the compounds of polycarboxylate D-2 separately with P1SAL0.68, P1SAL0.84 and TERSPERSE 2500 at the mass ratio of 1:1. All Nano-SC prepared by these three dispersants had a D90 particle size below 200 nm, suspension percentage above 99%, water separation proportion below 1%, excellent thermal storage stability, and also better wettability on banana leaf surface. Additionally, adding glycerin could effectively inhibit the agglomeration and austenogenization of pesticide nanoparticles, and thus improve the stability of Nano-SC. Finally, the farmland experiments indicated chlorantraniliprole Nano-SC prepared in this work had a significantly improved pesticide effect on first-instar rice leaf rollers than traditional micron-sized SC. This work provided a new dispersant with excellent performance for chlorantraniliprole Nano-SC as well as broadened the high value-added utilization of industrial lignin into pesticide Nano-SC field, which had great economic and environmental benefits.