Abstract
An α-imino-acidato ruthenium(II) complex, N-benzyl-1,2-didehydroglycinato bis(1,10-phenanthroline) ruthenium(II) complex ([Ru( N-Bn-gly-H 2 (phen) 2] +), was obtained by controlled-potential anodic oxidation of the corresponding α-amino-acidato ruthenium(II) complex ([Ru( N-Bn-gly) (phen) 2] +. The crystal structure of [Ru( N-Bn-gly-H 2) (phen) 2] Cl·H 2O·C 2H 5OH has been determined by single crystal X-ray diffraction. The benzene ring of the benzyl group of the α-imino-acidato moiety is stacked above one of the phenanthroline rings. The conformation of the benzyl group in solution, estimated by nuclear Overhauser effect measurement, is considered to be similar to that in the crystal.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
