Preparation and Luminous Performance of Ternary Complexes of Rare Earth Europium (III)

Abstract

Using Eu2O3 as source of tritium, anhydrous ethanol as solvent system, three β-diketone compounds of 2-thienyl trifluoroacetone (TTA), acetylacetone (Hacac), 1-(4-Methoxyphenyl)- 3-(4-tert-butylphenyl)-1,3-propanedione (Avobenzone) as first ligand and 1,10-phenanthroline (Phen) as second ligand, the three kinds europium (III) ternary complexes were prepared by precipitation method at 60 °C. The complexes were characterized by fluorescence spectroscopy (FS), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry and differential scanning calorimetry (TG-DSC) and color coordinates. The results show that three red light-emitting europium (III) ternary complexes can emit strong red characteristic fluorescence. Thereinto, Eu(TTA)3Phen has the best luminescent performance. The excitation spectrum of Eu(TTA)3Phen is 395 nm, the characteristic emission peak is at 612 nm, and the color coordinate is (0.66, 0.34). Eu(TTA)3Phen show good thermal stability which is decomposed more than 200 °C.