Abstract
A novel nanostructured magnetic composite materials for solid base catalyst composed of CoFe 2O 4 as the magnetic core and magnesium aluminum layered double hydroxide with OH − as interlayer anion (abbreviated as MgAl–OH-LDH) providing basic sites has been achieved. The catalyst has been characterized using XRD, IR, TG-DTA, BET, TEM, XPS, VSM and PSD analysis techniques, and evaluated by self-condensation of acetone. The results manifest that a MgAl–OH-LDH Brønsted base catalytic layer coats onto the surface of a magnetic core CoFe 2O 4 through Mg–O–Co(Fe) and/or Al–O–Co (Fe) linkage with particle size distribution in the range of 38–126 nm, and the catalyst acts high catalytic activity and selectivity in self-condensation of acetone. The diacetone alcohol conversion reaches 15.3% at 273 K. After easily recovery through an exterior magnetic field, high recovery rate of MgAl–OH-LDH/CoFe 2O 4 (98%) is gained, and high activity (14.1% and 13.6%) has still remained in the same two reactions.
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