Abstract
Three different thiosemicarbazone (TSC) ligands, BTSC, ClTSC, and MeTSC, derived from benzophenone, pâchlorobenzaldehyde, and mâmethoxybenzaldehyde, respectively, were complexed with K2PtCl4. The structures of the complexes were determined on the basis of elemental analyses, IR and 1H, 15N, and 13C NMR spectral studies, which support the formation of squareâplaner dimeric complexes of the type [LPtCl2PtL], where L is MeTSC and ClTSC, which are N,S containing bidentate ligands. The complex prepared with the ligand BTSC is of the type [L2PtCl2] where L acts as a monodendate ligand as confirmed by CHN analyses. Xâray powder analyses show that the complexes are crystalline.
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More From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
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