Abstract
The structures and hydrogen adsorption properties of {Cr3F(H2O)2O[(O2C)-C6H4-(CO2)]3・nH2O(n∼25)} (MIL-101) and its Pd composites have been investigated by X-ray diffraction (XRD) analysis, transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and specific surface area tests (BET). The as-prepared Pd/MIL-101 composites were microporous and maintained three-dimensional topology of MIL-101 before and after Pd loading that existed in the skeleton. A carbon bridge was formed between Pd metal and MIL-101 to improve the hydrogen storage. The loaded Pd reduced the hydrogen absorption enthalpy of MIL-101, and thus improved the storage of hydrogen compared with MIL-101. The diffusion coefficient reached 7.233 × 10−9 in the Pd/MIL-101 nanocomposites.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
