Preparation and fire extinguishing characteristics of inorganic solidified foam with large amount of slag

Abstract

ABSTRACT Aiming at the problems of conventional cement-based foam plugging and filling materials, such as large amount of cement, low utilization rate of solid waste, unclear bonding, and plugging mechanism, it was proposed that a kind of plugging and preventing fire material named inorganic solidified foam was prepared from industrial slag, cement, and water-based foam as the main raw materials. Based on the fluidity, expansion ratio and mechanical strength of solidified foam, it was determined that S105 slag powder with high content of 60%~65% and the optimal content of the chemical activator 6%. The dry density of solidified foam was about 410~450 kg/m3, and the compressive strength reached 0.5~0.55 MPa. The formation process, the bonding-reinforcement mechanism, and the fire prevention characteristic fire of solidified foam were explored. The results showed that solidified foam could significantly improve the pozzolanic activity of solid waste under the effect of physical and chemical synergy, promoted the hydration reaction of the material, increased the structural compactness of the hydration product of the material, further improving the strength. Fire-fighting experiments and field application exhibited that solidified foam could rapidly diffuse and accumulate to high places through crack channels, quickly extinguish and cool down, and coat loose high-temperature coal piles, showing excellent effect of preventing coal spontaneous combustion. Moreover, the field test results showed that the solidified foam could quickly plug the air leakage, and reduce the CO concentration in the air leakage are. Specifically, the CO concentration of high falling area decreased from 315 ppm to 22 ppm in 3 days, eventually stabilizing below 10 ppm, thereby timely inhibiting the development of spontaneous combustion fire.