Preparation and evaluation of cerium(IV) tungstate powder as inorganic exchanger in sorption of cobalt and europium ions from aqueous solutions

Abstract

Cerium(IV) tungstate powder was chemically synthesized and exploited as adsorbent material for the decontamination study of cobalt and europium ions from radioactive waste solutions under simulated conditions using batch technique. The influences of pH, particle size and temperature have been reported. The uptake of europium was found to be slightly greater than that of cobalt and the apparent sorption capacity increases with increase in temperature. Thermodynamic parameters such as changes in Gibbs free energy (Δ G°), enthalpy (Δ H°), and entropy (Δ S°) were calculated. The numerical value of Δ G° decreases with an increase in temperature, indicating that the sorption reaction of each ion was spontaneous and more favorable at higher temperature. The positive values of Δ H° correspond to the endothermic nature of sorption processes and suggested that chemisorption was the predominant mechanism. A comparison of kinetic models applied to the sorption rate data of each ion was evaluated for the pseudo first-order, the pseudo second-order, intraparticle diffusion and homogeneous particle diffusion kinetic models. The results showed that both the pseudo second-order and the homogeneous particle diffusion models were found to best correlate the experimental rate data. The numerical values of the rate constants and particle diffusion coefficients were determined from the graphical representation of the proposed models. Activation energy ( E a) and entropy (Δ S ‡) of activation were also computed from the linearized form of Arrhenius equation.